3M AUSTRALIA PTY LIMITED 3M NEW ZEALAND LTD
950 Pacific Highway 250 Archers Road
Pymble NSW 2073 Glenfield Auckland N.Z.
Phone: 136 136 Phone: (9) 444 4760
24HR EMERGENCY: 1800 097 146 (Australia only).
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MATERIAL SAFETY DATA SHEET
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Document ID : 10-3323-2 Issue date : 14/07/2006
Version : 2.00 Supersedes date : 19/02/2003
Document status : Issued
This MSDS has been prepared by 3M Australia Pty Ltd Toxicology Dept.
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1 PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME
3M(TM) FOAM FAST 74 CLASSIC SPRAY ADHESIVE AND 3M(TM) FOAM FAST 74
CYLINDER SPRAY ADHESIVE
DIVISION
AD - INDUSTRIAL ADHESIVES AND TAPES
3M Product ID
CS-0406-2031-5, AS-0104-0631-9, AS-0105-0631-9, AS-0105-0632-7,
AS-0104-2511-9, CS-0406-6972-6, 0357988, CS-0406-6932-0,
62-4991-0930-4, 62-4991-0931-2, 62-4991-4930-0, 62-4991-4935-9,
62-4991-4936-7, 62-4991-4937-5, 62-4991-4938-3
RECOMMENDED USE: Adhesive
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2 HAZARDS IDENTIFICATION
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NOTE: DANGEROUS GOODS. NON-HAZARDOUS SUBSTANCE.
POISONS SCHEDULE Not applicable.
Symbols
F+ (Extremely Flammable) N (Dangerous to Environment)
Risk Codes and Phrases
R12 Extremely flammable.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms. May cause long-term adverse
effects in the aquatic environment.
Safety Codes and Phrases
S16 Keep away from sources of ignition - No smoking.
S51 Use only in well ventilated areas.
S23C Do not breathe vapour or spray.
S24/25 Avoid contact with the skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S28A After contact with skin, wash immediately with plenty of soap
and water.
S61 Avoid release to the environment. Refer to special
instructions/safety data sheets.
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3 COMPOSITION
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Ingredient Name CAS number Percentage
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DIMETHYL ETHER 115-10-6 35 - 45
NON-VOLATILE COMPONENTS (Trade Secret)--- 20 - 30
PENTANE 109-66-0 20 - 30
ACETONE 67-64-1 7 - 13
NAPHTHOL SPIRITS 64742-48-9 1 - 5
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4 FIRST AID MEASURES
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EYE CONTACT
Flush eyes with large amounts of water. If signs/symptoms persist,
get medical attention.
SKIN CONTACT
Wash affected area with soap and water. If signs/symptoms develop,
get medical attention.
INHALATION
Remove person to fresh air. If signs/symptoms develop, get medical
attention.
IF SWALLOWED
Do not induce vomiting. Get immediate medical attention. Give person
two glasses of water. Never give anything by mouth to an unconscious
person.
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5 FIRE FIGHTING MEASURES
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SUITABLE EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry
chemical, carbon dioxide).
EXPOSURE HAZARDS DURING FIRE
Closed containers exposed to heat from fire may build pressure and
explode. Vapours may travel long distances along the ground or floor
to an ignition source and flash back.
FIRE FIGHTING PROCEDURES
Wear full protective equipment (Turnout Gear) and a self-contained
breathing apparatus (SCBA).
Combustion Products from Fire
Combustion Products from Fire are listed in Section 10, STABILITY AND
REACTIVITY.
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6 ACCIDENTAL RELEASE MEASURES (SPILL)
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Personal Precautions
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment.
Spill Response
Seal the container. Evacuate unprotected and untrained personnel from
hazard area. The spill should be cleaned up by qualified personnel.
Remove all ignition sources such as flames, smoking materials, and
electrical spark sources. Use only non-sparking tools. Ventilate
area with fresh air. Place leaking container in ventilation hood,
Clean up residue with an appropriate solvent selected by a qualified
and authorized person. Read and follow safety precautions on the
solvent label and MSDS. Collect the resulting residue containing
solution. Place in a metal container approved for transportation by
appropriate authorities. Dispose of collected material as soon as
possible.
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7 HANDLING AND STORAGE
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Conditions for Safe Storage
Refer to Incompatibility - Materials to Avoid.
Incompatibility - Materials to Avoid
Store away from acids. Store away from heat. Store out of direct
sunlight.
EXPLOSION AVOIDANCE
Keep away from heat, sparks, open flame, pilot lights and other
sources of ignition.
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8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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DIMETHYL ETHER (115-10-6)
NATIONAL EXPOSURE STANDARDS: TWA 400ppm 760mg/m3
STEL 500ppm 950mg/m3
PENTANE (109-66-0)
NATIONAL EXPOSURE STANDARDS: TWA 600ppm 1770mg/m3
STEL 750ppm 2210mg/m3
ACETONE (67-64-1)
NATIONAL EXPOSURE STANDARDS: TWA 500ppm 1185mg/m3 STEL
1000ppm 2375mg/m3
Special Information, Exposure/Protection
The extent to which the following recommendations for exposure
control and protection are observed should depend on the risk
assessment undertaken for the specific conditions under which this
product is used, including occupational hygiene measurements.
Recommended Ventilation
Use with appropriate local exhaust ventilation. Do not use in a
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confined area or areas with little or no air movement. Use general
dilution ventilation and/or local exhaust ventilation to control
airborne exposures to below Occupational Exposure Limits and/or
control mist, vapor, or spray. If ventilation is not adequate, use
respiratory protection equipment. Do not use in a confined area or
areas with little or no air movement. If exhaust ventilation is not
adequate, use appropriate respiratory protection. Provide ventilation
adequate to control vapor concentrations below recommended exposure
limits and/or control spray or mist.
Eye Protection
Avoid eye contact with vapour, spray, or mist. During operations in
which eye exposure is likely, the following should be worn alone, or
in combination, as appropriate: Safety glasses with side shields.
Select and use eye protection in accordance with AS/NZS 1336. Eye
protection should comply with the performance specifications of
AS/NZS 1337.
Hand Protection
Gloves made from one of the following material(s) are recommended
(Australian Standard AS/NZS 2161): Nitrile rubber. Polyvinyl alcohol.
Skin Protection
Avoid skin contact.
Respiratory Protection
Select one of the following approved respirators based on airborne
concentration of contaminants and in accordance with regulations:
Half facepiece or fullface air-purifying respirator with organic
vapour filters. Select and use respirators according to AS/NZS 1715.
Respirators should comply with AS/NZS 1716 performance
specifications. For information about respirators, call 3M on 1800
024 464.
Prevention of Accidental Ingestion
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
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9 PHYSICAL/CHEMICAL PROPERTIES
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Appearance and Odour Orange liquid in aerosol;
sweet/fruity odour
pH Not determined
Vapour pressure CONDITIONS: Compressed gas
Vapour density > 2 (Air=1)
Boiling point Not applicable
Melting point Not determined
Water Solubility NIL
Specific gravity 0.725
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Flash point -45.6 C TCC (Propellant)
Flammable Limits - LEL 1 % VOL
Flammable Limits - UEL Flammable gas
Autoignition temperature Not determined
Volatile organic compounds (VOC) Approx. 66 % by wt
content
Evaporation rate 2 (Ether=1)
Viscosity Not applicable
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10 STABILITY AND REACTIVITY
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Stability
Hazardous polymerisation will not occur. Stable.
Materials to Avoid
Heat
Hazardous Decomposition Products
Aldehydes during combustion.
Hydrocarbons during combustion.
Carbon monoxide during combustion.
Carbon dioxide during combustion.
Ketones during combustion.
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11 TOXICOLOGICAL INFORMATION
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Effects from Eye Contact
Moderate Eye irritation: Signs/symptoms can include redness,
swelling, pain, tearing and blurred or hazy vision.
Effects from Skin Contact
Mild Skin Irritation: Signs/symptoms may include localized redness,
swelling, and itching.
Effects from Inhalation
May be absorbed following inhalation and cause target organ effects.
Upper Respiratory Tract Irritation: Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat
pain.
Intentional concentration and inhalation may be harmful or fatal.
Effects from Ingestion
May be absorbed following ingestion and cause target organ effects.
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, nausea, diarrhoea and vomiting.
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Other Toxicological Information
Central Nervous System (CNS) Depression: Signs/symptoms may include
headache, dizziness, drowsiness, uncoordination, nausea, slowed
reaction time, slurred speech, giddiness, and unconsciousness.
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12 ECOLOGICAL INFORMATION
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Environmental Data
Not determined
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13 DISPOSAL CONSIDERATIONS
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Product as Sold
Incinerate in a permitted hazardous waste incinerator. As a disposal
alternative, dispose of waste product in a permitted hazardous waste
facility. Incinerate at a facility equipped to handle gaseous waste.
Special Instructions for Disposal
Recycle empty aerosol containers where available.
Incinerate in a permitted hazardous waste incinerator in the
presence of a combustible material. Disposal facilities must be
capable of handling aerosol cans. Dispose of empty product containers
in a sanitary landfill. Dispose of completely absorbed waste product
in a facility permitted to accept chemical wastes. Contact your local
waste authority to determine suitable disposal methods.
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14 TRANSPORT INFORMATION
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ADG (Road/Rail)
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UN NUMBER UN 1950
PROPER SHIPPING NAME AEROSOLS, FLAMMABLE
DANGEROUS GOODS CLASS 2.1
SUBSIDIARY RISK NONE ALLOCATED
PACKING GROUP NONE ALLOCATED
IATA (Airfreight)
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UN NUMBER UN 1950
PROPER SHIPPING NAME AEROSOLS, FLAMMABLE
DANGEROUS GOODS CLASS 2.1
SUBSIDIARY RISK NONE ALLOCATED
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PACKING GROUP NONE ALLOCATED
IMO (Seafreight)
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UN NUMBER UN 1950
PROPER SHIPPING NAME AEROSOLS, FLAMMABLE
DANGEROUS GOODS CLASS 2.1
SUBSIDIARY RISK NONE ALLOCATED
PACKING GROUP NONE ALLOCATED
SPECIAL INSTRUCTIONS: IERG 49
LIMITED QUANTITY BY SEA FREIGHT
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15 REGULATORY INFORMATION
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Product Certifications
AICS - Yes: components checked
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16 OTHER INFORMATION
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REASON FOR REISSUE
This MSDS has been revised because 3M has adopted the 16-section
ANSI/ISO format. The potential hazards of the product have not
changed. We encourage you to re-read the MSDS and review the
information.
The information on this data sheet represents our current data and best
opinion as to the proper use in handling of this product under normal
conditions. Any use of the product which is not in conformance with
this data sheet, which involves using the product, or otherwise that in
accordance with instructions of use on product packaging is the
responsibility of the user. If clarification or further information is
needed to ensure that an appropriate risk assessment can be made, the
user should contact the Snr Regulatory Services Officer on
(02)9498-9287.